Discovery and development
The first known report of a light-emitting solid-state diode was made in 1907 by the British experimenter H. J. Round of Marconi Labs. Russian Oleg Vladimirovich Losev independently created the first LED in the mid 1920s; his research, though distributed in Russian, German and British scientific journals, was ignored, [5] [6] and no practical use was made of the discovery for several decades. Rubin Braunstein of the Radio Corporation of America reported on infrared emission from gallium arsenide (GaAs) and other semiconductor alloys in 1955. [7] . Braunstein observed infrared emission generated by simple diode structures using GaSb, GaAs, InP, and Ge-Si alloys cooled by liquid nitrogen to 77 K. Experimenters at Texas Instruments, Bob Biard [8] and Gary Pittman, found in 1961 that gallium arsenide gave off infrared radiation when electric current was applied. Biard and Pittman were able to establish the priority of their work and received the patent for the infrared light-emitting diode.
The first practical visible-spectrum (red) LED was developed by Nick Holonyak Jr. in 1962, then of the General Electric Company and later with the University of Illinois at Urbana-Champaign[9] and is seen as the "father of the light-emitting diode". [10] Holonyak's former graduate student, M. George Craford, invented in 1972 the first yellow LED and 10x brighter red and red-orange LEDs. [11]
Shuji Nakamura of Nichia Corporation of Japan demonstrated the first high-brightness blue LED based on InGaN, borrowing on critical developments in GaN nucleation on sapphire substrates and the demonstration of p-type doping of GaN which were developed by I. Akasaki and H. Amano in Nagoya. In the 1995 Alberto Barbieri at the Cardiff University Laboratory (GB) investigated the Efficiency and Reliability of high-brightness LED demonstrating very high result by using a transparent contact made by indium tin oxide (ITO) on (AlGaInP/GaAs) LED. The existence of the blue LED and high efficiency quickly carried to the first white LED, which employed a Y3Al5O12:Ce, or "YAG", phosphor coating to mix yellow (down-converted) light with blue to produce light that appears white. Nakamura was awarded the 2006 Millennium Technology Prize for his invention.[12]
[edit] Practical use
The first commercial LEDs were commonly used as replacements for incandescent indicators, and in seven-segment displays, first in expensive equipment such as laboratory and electronics test equipment, then later in such appliances as TVs, radios, telephones, calculators, and even watches. These red LEDs were bright enough only for use as indicators, as the light output was not enough to illuminate an area. Later, other colors became widely available and also appeared in appliances and equipment. As the LED materials technology became more advanced, the light output was increased, while maintaining the efficiency and the reliability to an acceptable level, causing LEDs to become bright enough to be used for illumination.
Most LEDs were made in the very common 5 mm T13and 3 mm T1 packages, but with higher power, it has become increasingly necessary to shed excess heat in order to maintain reliability, so more complex packages adapted for efficient heat dissipation are becoming common. Packages for state-of-the-art high power LEDs bear little resemblance to early LEDs (see, for example, Philips Lumileds).
|